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Reaction of hexachlorocyclopentadiene with some organosilicon compounds that contain the -CφC-Si(Ch3)3 grouping

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

A study was made of the diene condensation of hexachlorocyclopentadiene with trimethylsilyldiacetylene, pentamethyl(ethynyl)-1,2-disilylethylene, and pentamethyl(ethynyl)-1,2-disilylacetylene, and also with pentamethyl(ethynyl)disiloxane. The presence of a silicon atom between the multiple bonds sharply lowers the reactivity of the studied dienophiles.

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Literature cited

  1. N. V. Komarov, M. F. Shostakovskii, and T. D. Burnashova, Zh. Obshch. Khim.,38, 1398 (1968).

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  2. O. G. Yarosh, N. V. Komarov, and M. F. Shostakovskii, Izv. Akad. Nauk SSSR, Ser. Khim., 1639 (1970).

  3. O. G. Yarosh, N. V. Komarov, and Z. G. Ivanova, Izv. Akad. Nauk SSSR, Ser. Khim., 2122 (1972).

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Authors and Affiliations

  1. Irkutsk Institute of Organic Chemistry, Siberian Branch of the Academy of Sciences of the USSR, USSR

    M. G. Voronkov, T. D. Burnashova, O. G. Yarosh & N. V. Komarov

  2. Kuban State University, Krasnodar

    M. G. Voronkov, T. D. Burnashova, O. G. Yarosh & N. V. Komarov

Authors
  1. M. G. Voronkov
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  2. T. D. Burnashova
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  3. O. G. Yarosh
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  4. N. V. Komarov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2621–2623, November, 1974.

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Voronkov, M.G., Burnashova, T.D., Yarosh, O.G. et al. Reaction of hexachlorocyclopentadiene with some organosilicon compounds that contain the -CφC-Si(Ch3)3 grouping. Russ Chem Bull 23, 2530–2531 (1974). https://doi.org/10.1007/BF00922150

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  • DOI: https://doi.org/10.1007/BF00922150

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