Reaction of π-cyclopentadienyl-(σ-ferrocenoylmethyl) iron dicarbonyl with electrophilic reagents

  • A. N. Nesmeyanov
  • É. G. Perevalova
  • L. I. Leont'eva
  • O. V. Grigor'eva
Brief Communications

Conclusions

  1. 1.

    π-Cyclopentadienyl-(σ-ferrocenoylmethyl)iron dicarbonyl reacts with HgBr2 or CH3-COC1 with a cleavage of the Fe-C σ-bond.

     
  2. 2.

    Carboxonium salts are formed when π-cyclopentadienyl-(σ-ferrocenoylmethyl)iron dicarbonyl is reacted with mineral acids.

     
  3. 3.

    HC1 and I2 easily cleave the Hg-C bond in bromomercuriacetylferrocene.

     

Keywords

Iron Mineral Acid Dicarbonyl Electrophilic Reagent HgBr2 

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Literature cited

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Copyright information

© Plenum Publishing Corporation 1976

Authors and Affiliations

  • A. N. Nesmeyanov
    • 1
  • É. G. Perevalova
    • 1
  • L. I. Leont'eva
    • 1
  • O. V. Grigor'eva
    • 1
  1. 1.M. V. Lomonosov Moscow State UniversityUSSR

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