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Synthesis and some properties of aminooxyalkylcelluloses

  • Organic and Biological Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The previously unknown aminooxyalkylcelluloses have been synthesized by alkylation of cellulose with N-substituted ω-haloalkylhydroxylamines.

  2. 2.

    The prepared aminooxyalkylcelluloses are weak ion-exchangers, readily react with many classes of organic compounds, and are stable during storage.

  3. 3.

    Methods have been developed for the preparation of aminooxyalkylcelluloses with different lengths of the pendant H2NO group on the polysaccharide framework.

  4. 4.

    Sorbents were prepared, based on the aminooxyalkylcelluloses, which contained a covalently bonded coenzyme (pyridoxal-5′-phosphate), a substrate (α-ketoglutaric acid) and functional groups, able to react with certain functional groups of biopolymers.

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Literature cited

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Authors and Affiliations

  1. Institute of Molecular Biology, Academy of Sciences of the USSR, Moscow

    A. A. Nedospasov & R. M. Khomutov

Authors
  1. A. A. Nedospasov
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  2. R. M. Khomutov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1136–1141, May, 1976.

Main features of recent work which was reported at the Soviet-American Symposium on Pyridoxal Catalysis, Leningrad, 1975.

The authors thank N. P. Bazhulina for assistance in recording the fluorescence spectra.

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Nedospasov, A.A., Khomutov, R.M. Synthesis and some properties of aminooxyalkylcelluloses. Russ Chem Bull 25, 1105–1110 (1976). https://doi.org/10.1007/BF00922002

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  • DOI: https://doi.org/10.1007/BF00922002

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