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Transformed steroids

Communication 78. N-acetates of 16,17α-epimino-20-ketosteroids in ring-opening reactions by thiocyanic acid

  • Organic and Biological Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

We determined the conditions for opening the aziridine ring of the 16,17α-acetylepimines of 20-ketosteroids with thiocyanic acid and obtained the 17α-acetylamines of 20-ketopregnenes that contain the thiocyanato and thiol functions in position 16.

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Literature cited

  1. A. V. Kamernitskii, L. E. Kulikova, I. S. Levina, and V. B. Muratov, Izv. Akad. Nauk SSSR, Ser. Khim.,1976, 1129.

  2. F. Winternitz and C. R. Engel, Steroids,6, 805 (1966).

    Google Scholar 

  3. A. A. Akhrem, A. V. Kamernitskii, and A. V. Skorova, USSR Patent 380,649 (1971); Byull. Izobr., No. 21 (1973).

  4. G. Drefahl, K. Ponseld, and B. Schönecker, Z. Chem.,5, 268 (1965).

    Google Scholar 

  5. K. Ponsold, B. Schönecker, and P. Groh, Chem. Ber.,99, 3485 (1966).

    Google Scholar 

  6. A. A. Akhrem, V. A. Dubrovskii, A. V. Kamernitskii, and A. V. Skorova, Izv. Akad. Nauk SSSR, Ser. Khim.,1969, 2792.

  7. B. R. Johnston, A. Patchett, and B. Windholz, USA Patent 3,487,076 (1969); C. A.,72, 67210 (1970).

    Google Scholar 

  8. D. B. R. Johnston, C. A. Sawicki, T. B. Windholz, and A. A. Patchett, Steroids,11, 113 (1968).

    Google Scholar 

  9. A. A. Akhrem, Z. I. Istomina, A. M. Turuta, and G. A. Kogan, Izv. Akad. Nauk SSSR, Ser. Khim.,1972, 1354.

  10. S. K. Banerjee, D. Chakravarti, R. N. Chakravarti, and M. N. Mitra, Tetrahedron,24, 6459 (1968).

    Google Scholar 

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See [1] for Communication 77.

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1132–1136, May, 1976.

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Kamernitskii, A.V., Turuta, A.M. & Fadeeva, T.M. Transformed steroids. Russ Chem Bull 25, 1101–1105 (1976). https://doi.org/10.1007/BF00922001

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  • DOI: https://doi.org/10.1007/BF00922001

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