Conclusions
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1.
Catalytic decomposition of aliphatic diazo compound under the effect of tungsten chlorides leads to initiation of the chain process of opening of cycloolefins.
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2.
The possibility was shown on the example of the organotungsten compound (CH3)3SiCH2-WCl5 of using oxidation-reduction systems to generate carbene active centers at low temperatures.
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3.
Certain aspects of the chain stage of the double-bond redistribution process were examined in connection with the relative reactivity of carbene active centers.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 1084–1089, May, 1976.
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Dolgoplosk, B.A., Makovetskii, K.L., Tinyakova, E.I. et al. Role of carbene complexes in chain initiation and propagation of double-boot redistribution reactions. Russ Chem Bull 25, 1053–1057 (1976). https://doi.org/10.1007/BF00921990
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DOI: https://doi.org/10.1007/BF00921990