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Effect of component ratios and acidity of alumosilicate catalysts on oligomerization of ethylene and isobutylene

  • Organic and Biological Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The activity of catalysts containing 2 and 20% NiO on SiO2-Al2O3 in dimerization reactions of ethylene depends on the Al2O3 content.

  2. 2.

    The degree of oligomerization of isobutylene and double-bond migration in n-butenes, formed by ethylene dimerization, changes in agreement with the total acidity of the catalyst on 2% NiO-SiO2-Al2O3 catalyst.

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Literature cited

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR

    A. L. Lapidus, V. V. Mal'tsev, A. A. Slinkin, M. I. Loktev & Ya. T. Éidus

Authors
  1. A. L. Lapidus
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  2. V. V. Mal'tsev
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  3. A. A. Slinkin
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  4. M. I. Loktev
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  5. Ya. T. Éidus
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Additional information

Deceased.

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 1080–1084, May, 1976.

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Lapidus, A.L., Mal'tsev, V.V., Slinkin, A.A. et al. Effect of component ratios and acidity of alumosilicate catalysts on oligomerization of ethylene and isobutylene. Russ Chem Bull 25, 1049–1053 (1976). https://doi.org/10.1007/BF00921989

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  • DOI: https://doi.org/10.1007/BF00921989

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