Conclusions
-
1.
The catalytic properties of the Ni forms of various types of synthetic zeolites in the reaction of benzene with ethylene are determined by their structure, composition, and conditions under which they are used.
-
2.
The NiNaA zeolites accelerate only the dimerization of C2H4, and are inactive in the alkylation of C6H6 with olefins. From benzene and ethylene it is possible to obtain on NiX and NiY either predominantly sec-butylbenzene (SBB) (selectivity 80–86%) or SBB and butenes in approximately equal amounts.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Literature cited
Kh. M. Minachev, Kinet. Katal.,11, 413 (1970).
A. L. Lapidus, R. V. Avetisyan, Ya. I. Isakov, Kh. M. Minachev, and Ya. T. Éidus, Neftekhimiya,10, 648 (1970).
A. L. Lapidus, Ya. I. Isakov, A. A. Slinkin, R. V. Avetisyan, Kh. M. Minachev, and Ya. I. Eidus, Izv. Akad. Nauk SSSR, Ser. Khim.,1971, 1904.
Kh. M. Minachev, Ya. I. Isakov, G. V. Antoshin, V. P. Kalinin, and E. S. Shpiro, Izv. Akad. Nauk SSSR, Ser. Khim.,1973, 2527.
Ya. I. Isakov, Kh. M. Minachev, and V. P. Kalinin, Izv. Akad. Nauk SSSR, Ser. Khim.,1976, 498.
Kh. M. Minachev, Ya. I. Isakov, V. P. Kalinin, A. L. Lapidus, and Ya. T. Eidus, Izv. Akad. Nauk SSSR, Ser. Khim.,1974, 1334.
G. T. Kerr, J. Phys. Chem.,72, 2594 (1968).
J. V. Smith, Advances Chem. Ser.,101, 171 (1971).
J. A. Rabo and M. L. Poutsma, Advances Chem. Ser.,102, 260 (1971).
C. L. Angell and P. C. Schaffer, J. Phys. Chem.,70, 1413 (1966).
V. I. Bogomolov, N. V. Mirzabekova, Ya. I. Isakov, L. O. Golender, and Kh. M. Minachev, Izv. Akad. Nauk SSSR, Ser. Khim.,1972, 1697.
P. Gallezot and B. Imelik, J. Phys. Chem.,77, 652 (1973).
T. A. Egerton and F. S. Stone, J. Chem. Soc., Faraday Trans. 1,69, 22 (1973).
P. Gallezot, Y. Ben Taarit, and B. Imelik, J. Catalysis,16, 48 (1972); J. Phys. Chem.,77, 2556 (1973).
Kh. M. Minachev, Ya. I. Isakov, and V. P. Kalinin, Izv. Akad. Nauk SSSR, Ser. Khim.,1975, 1785.
M. F. Guilleux and J. F. Tempere, Compt. Rend.,272C, 2105 (1971).
T. A. Egerton and J. C. Vickerman, J. Chem. Soc., Faraday Trans. 1,69, 39 (1973).
A. A. Kubasov, Zh. Fiz. Khim.,48, 2088 (1974).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1073–1080, May, 1976.
Rights and permissions
About this article
Cite this article
Minachev, K.M., Isakov, Y.I., Kalinin, V.P. et al. Study of polyfunctional zeolite catalysts. Russ Chem Bull 25, 1041–1048 (1976). https://doi.org/10.1007/BF00921988
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00921988