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νAs=S in infrared and Raman spectra

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The As=S bond displays strong absorption bands in the infrared spectrum and intense lines in the Raman spectrum in the 460- to 500-cm−1 region.

  2. 2.

    In the general case, the νAs=S frequency may be correlated with the Kabachnik constants σΦ for the substituents and with the phosphoryl shift π-constants. Partial correlations of the integral intensities of the absorption bands of the As=S bond with σΦ were noted.

  3. 3.

    The data which has been obtained is in accordance with contemporary ideas concerning the multiple character of the As=S bond.

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Literature cited

  1. R. A. Zingaro, R. E. McClothin, and R. M. Hedges, Trans. Faraday Soc.,59, 798 (1963).

    Google Scholar 

  2. F. L. Kolar, R. A. Zingaro, and J. Laane, J. Mol. Struct.,18, 319 (1973).

    Google Scholar 

  3. Ed. Moslowsky, J. Organometal. Chem.,70, 153 (1974).

    Google Scholar 

  4. R. R. Shagidullin, S. V. Izosimova, I. A. Lamanova, and Yu. G. Galyametdinov, Materials of the Scientific Conference, Institute of Organic and Physical Chemistry, Academy of Sciences of the USSR [in Russian], Kazan' (1972), p. 211.

    Google Scholar 

  5. R. R. Shagidullin, S. V. Izosimova, and I. A. Lamanova, Izv. Akad. Nauk SSSR, Ser. Khim., 2788 (1973).

  6. R. R. Shagidullin, I. A. Lamanova, and A. K. Urazgil'deeva, Dokl. Akad. Nauk SSSR,174, 1359 (1967).

    Google Scholar 

  7. T. A. Mastryukova and M. I. Kabachnik, Uspekhi Khim.,38, 1751 (1969).

    Google Scholar 

  8. R. A. Chittenden and L. C. Thomas, Spectrochim. Acta,20, 467 (1964).

    Google Scholar 

  9. R. R. Shagidullln and I. A. Lamanova, Izv. Akad. Nauk SSSR, Ser. Khim., 1235 (1969).

  10. R. R. Shagidullin, I. A. Lamanova, and L. V. Awakumova, Materials of the Scientific Conference, Institute of Organic and Physical Chemistry of the Academy of Sciences of the USSR [in Russian], Kazan' (1970), p. 82.

    Google Scholar 

  11. A. V. Iogansen, Opt. Spektr.,5, 813 (1964).

    Google Scholar 

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Author information

Authors and Affiliations

  1. Kazan' Branch of the Academy of Sciences of the USSR, The A. E. Arbuzov Institute of Organic and Physical Chemistry, USSR

    R. R. Shagidullin & S. V. Izosimova

Authors
  1. R. R. Shagidullin
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  2. S. V. Izosimova
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1045–1048, May, 1976.

The authors express their sincere thanks to Professor B. D. Chernokal'skii and his coworkers for making the compounds used in this investigation available to them.

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Shagidullin, R.R., Izosimova, S.V. νAs=S in infrared and Raman spectra. Russ Chem Bull 25, 1017–1021 (1976). https://doi.org/10.1007/BF00921983

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  • DOI: https://doi.org/10.1007/BF00921983

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