Vibrational spectra of the hexaalkyldielementooxanes-derivatives of the group IVB elements

  • M. G. Voronkov
  • S. G. Shevchenko
  • É. I. Brodskaya
  • R. G. Mirskov
  • A. M. Sklyanova
  • Yu. L. Frolov
Physical Chemistry
  • 16 Downloads

Conclusions

On the basis of the calculation of the frequencies and form of the normal vibrations for hexaalkyldielementooxanes (C2H5)3MOM(C2H5)3 (M is an element from the Group IVB) and the existence of a correlation between ν as MOM and kMO and ΔνOH, it is shown that a change in the frequency of the antisymmetrical valence vibrations for the M-O-M group is mainly due to dynamic effects in the M-O-M system.

Keywords

Dynamic Effect Vibrational Spectrum Normal Vibration Valence Vibration Antisymmetrical Valence 

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Copyright information

© Plenum Publishing Corporation 1976

Authors and Affiliations

  • M. G. Voronkov
    • 1
  • S. G. Shevchenko
    • 1
  • É. I. Brodskaya
    • 1
  • R. G. Mirskov
    • 1
  • A. M. Sklyanova
    • 1
  • Yu. L. Frolov
    • 1
  1. 1.Siberian Branch of the Academy of Science of the USSRIrkutsk Institute of Organic ChemistryUSSR

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