Conclusions
-
1.
A new additive scheme is given for calculating the molecular refraction for ten spectral lines. The constants for the atoms, groups, and bonds in the new scheme are referred to the hydrogen atom as a standard fragment of the molecule and do not contain contributions due to conjugation, superconjugation, and spatial effects.
-
2.
Specific correlation equations are obtained, which relate the refraction constants of the molecule's fragments with the wavelength of light.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Literature cited
B. V. Ioffe, Refractometric Methods in Chemistry [in Russian], Khimiya, Leningrad (1974).
B. A. Zaitsev, Reactivity of Organic Compounds [in Russian],6, (1969), pp. 398, 414, 1034, and 1045.
O. Exner, Collect. Czech. Chem. Communs.,31, 3222 (1966).
P. Wulff, Z. phys. Chem.B21, 368 (1933).
A. F. Forziati, J. Res. Nat. Bur. Standards,44, 373 (1950); D. L. Camin, A. F. Forziati, and F. D. Rossini, J. Phys. Chem.,58, 440 (1954); D. L. Camin, F. D. Rossini, ibid.,59, 1173 (1955); F. D. Rossini, K. S. Pitzer, R. L. Arnett, R. M. Braun, and G. C. Pimentel, Selected Values of Physical and Thermodynamic Properties Hydrocarbons and Related Compounds, Pittsburgh, Carnegie Press, (1953); R. R. Dreisbach, Physical Properties of Chemical Compounds, Am. Chem. Soc., Washington, (1955–1961).
J. Timmermans, Physicochemical Constants of Pure Organic Compounds, Amsterdam-London-New York. (1950, 1965),1,2, J. P. Wibaut, H. Hoog, S. L. Langedijk, J. Overhoff, and J. Smittenberg, Rec. trav. chim.,58, 329 (1939); J. P. Wibaut and H. Geldof, ibid.,65, 125 (1946).
D. L. Camin and F. D. Rossini, J. Phys. Chem.,60, 1446 (1956).
P. Pomerantz, A. Fookson, T. W. Mears, S. Rothenberg, and L. Frank, J. Res. Nat. Bur. Standards,52, 59 (1954).
K. N. Campbell and L. T. Eby, J. Am. Chem. Soc.,63, 216, 2683 (1941).
R. Grzeskowiak, G. H. Jeffery, and A. I. Vogel, J. Chem. Soc.,1960, 4710.
B. Wojtkowiak, Ann. chim.,9 (1–2), 5 (1964).
A. L. Henne and K. W. Greenlee, J. Am. Chem. Soc.,67, 484 (1945).
K. N. Campbell and S. L. Eveslage, ibid., p. 1851; K. N. Campbell and M. J. O'Conner, ibid.,61, 2897 (1939).
H. H. Wenzke and R. P. Allard, ibid.,56, 858 (1934).
J. R. Johnson, A. M. Schwartz, and T. L. Jacobs, ibid.,60, 1882 (1938).
T. Kvte, G. H. Jeffery, and A. I. Vogel, J. Chem. Soc.,1960, 4454; D. M. Cowan, G. H. Jeffery, and A. I. Vogel, ibid., 1940, 171;1946, 136;1948, 610 1814.
T. E. Smith and R. F. Bonner, Ind. Eng. Chem.,43, 1169 (1951).
R. R. Dreisbach and R. A. Martin, ibid.,41, 2875 (1949).
P. Ceuterick, Bull. Soc. chim. belg.,45, 553 (1936).
Y. R. Naves, Helv. chim. acta,26, 1035 (1943).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1029–1035, May, 1976.
Rights and permissions
About this article
Cite this article
Zaitsev, B.A. New additive scheme for calculating the molecular refraction and dispersion for different wavelengths. Russ Chem Bull 25, 1003–1009 (1976). https://doi.org/10.1007/BF00921980
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00921980