Conclusions
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1.
Chemical polarization of nuclei13C was observed in the products of reactions between tetraalkyl ammonium salts of hydroperoxides and CCl4.
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2.
The initial stages of the reaction take place in accordance with an ionic mechanism; the intermediate unstable products formed under these circumstances (hypochloride and carbenes) initiate radical reactions, in whose final products there is set up chemical polarization of the nuclei.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1001–1005, May, 1976.
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Pershin, A.D., Lapshin, N.M. & Buchachenko, A.L. Chemical polarization of nuclei. Russ Chem Bull 25, 976–980 (1976). https://doi.org/10.1007/BF00921975
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DOI: https://doi.org/10.1007/BF00921975