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The role of anion-radicals of p-nitrochlorobenzene and of oxygen in the formation of p-nitrophenol by the interaction of p-nitrochlorobenzene with sodium methylate

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    We discovered an S-shaped character for the kinetics of buildup of p-nitrophenolate, and an effect of oxygen on the rate of formation of p-nitrophenolate, in the reaction of p-nitrochlorobenzene with sodium methylate.

  2. 2.

    A scheme has been proposed for the formation of p-nitrophenolate, with the participation of anion radicals of p-nitrochlorobenzene and oxygen. Formation of anion radicals of p-nitrochlorobenzene is a reaction proceeding in parallel with the substitution reaction.

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Authors and Affiliations

  1. The Institute of Heteroorganic Compounds of the Academy of Sciences of the USSR, Moscow

    S. P. Solodovnikov

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  1. S. P. Solodovnikov
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 996–1000, May, 1976.

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Solodovnikov, S.P. The role of anion-radicals of p-nitrochlorobenzene and of oxygen in the formation of p-nitrophenol by the interaction of p-nitrochlorobenzene with sodium methylate. Russ Chem Bull 25, 971–976 (1976). https://doi.org/10.1007/BF00921974

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  • DOI: https://doi.org/10.1007/BF00921974

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