Mechanism of the reaction of saturated hydrocarbons with ozone

  • A. A. Popov
  • S. K. Rakovskii
  • D. M. Shopov
  • L. V. Ruban
Physical Chemistry


The kinetic parameters of the reaction of cycloparaffins from C5 to C12 with ozone were obtained experimentally. From a comparison of the preexponential factors Acalc and Aexp, it was concluded that the structure of the transition complex (RH...O3) is linear, which permits us to give preference to the mechanism RH + O3 →> R. + HO. + O2.


Ozone Hydrocarbon Kinetic Parameter Preexponential Factor Saturated Hydrocarbon 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    C. Schubert and R. Pease, J. Amer. Chem. Soc.,78, 2044, 5553 (1956).Google Scholar
  2. 2.
    S. D. Razumovskii, Dissertation [in Russian], Moscow (1972).Google Scholar
  3. 3.
    D. G. Williamson and R. Cvetanovic, J. Amer. Chem. Soc.,90, 4248 (1968);92, 2949 (1970).Google Scholar
  4. 4.
    L. G. Galimova, V. D. Komissarov, and E. T. Denisov, Izv. Akad. Nauk SSSR, Ser. Khim., 307 (1973).Google Scholar
  5. 5.
    S. D. Razumovskii and G. E. Zaikov, Dokl. Akad. Nauk SSSR,192, 1313 (1970).Google Scholar
  6. 6.
    V. N. Kondrat'ev and E. E. Nikitin, Kinetics and Mechanism of Gas-Phase Reactions [in Russian], Nauka (1974), p. 48.Google Scholar
  7. 7.
    G. A. Gamilton, B. S. Ribner, and T. M. Helliman, Advances Chem. Ser.,77, 15 (1968).Google Scholar
  8. 8.
    S. D. Razumovskii and G. E. Zaikov, Ozone and Its Reaction with Organic Compounds [in Russian], Nauka (1974), p. 214.Google Scholar
  9. 9.
    V. Darvin and L. Albright, Ind. and Eng. Chem. Process. Des. and Develop.,4, 61 (1965).Google Scholar
  10. 10.
    M. Whiting, Int. Symp. Oxid., Prepr., San Francisco,2, 267 (1967).Google Scholar
  11. 11.
    W. C. Schumb, C. N. Satterfield, and R. L. Wentworth, Hydrogen Peroxide, Reinhold (1955).Google Scholar
  12. 12.
    S. Glasstone, K. Laidler, and H. Eyring, The Theory of Absolute Reaction Rates [Russian translation], IL (1948).Google Scholar
  13. 13.
    M. V. Bazilevskii, The Method of Molecular Orbitals and the Reactivity of Organic Molecules [in Russian], Khimiya (1969).Google Scholar
  14. 14.
    M. V. Bazilevskii and E. A. Trosman, Uspekhi Khimii,41, 3 (1972).Google Scholar
  15. 15.
    Concise Chemical Encyclopedia [in Russian], Vol. 3, “Sovet-skaya Entsiklopediya,” Moscow (1964), p. 654.Google Scholar
  16. 16.
    I. N. Godnev, Calculation of Thermodynamic Functions according to Molecular Data [in Russian], GITTL, Moscow (1956).Google Scholar
  17. 17.
    E. Eliel, N. Allinger, S. Angyal, and G. Morrison, Conformational Analysis, Wiley, Interscience (1965).Google Scholar
  18. 18.
    S. Benson, Thermochemical Kinetics [Russian translation], Mir (1971); Fundamentals of Chemical Kinetics [Russian translation], Mir (1964).Google Scholar
  19. 19.
    K. S. Pitzer, J. Chem. Phys.,14, 239 (1946).Google Scholar
  20. 20.
    E. Rabinowitch, Trans. Faraday Soc.,33, 1225 (1937).Google Scholar
  21. 21.
    M. Evans and M. Polany, Trans. Faraday Soc.,32, 1333 (1936).Google Scholar
  22. 22.
    R. Bell, Trans. Faraday Soc.,33, 496 (1937).Google Scholar

Copyright information

© Plenum Publishing Corporation 1976

Authors and Affiliations

  • A. A. Popov
    • 1
  • S. K. Rakovskii
    • 1
  • D. M. Shopov
    • 1
  • L. V. Ruban
    • 1
  1. 1.Institute of Chemical PhysicsAcademy of Sciences of the USSRMoscow

Personalised recommendations