Conclusions
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1.
The catalytic activity of new complexes of Pt (II)-Sn (II) with dimethylacetamide and DMF in isomerization and hydrogenation reactions of compounds containing a C=C bond is greater than the activity of the Pt-SnCl3 complex by a factor of 4–5.
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2.
All the examined complexes catalyzed the selective hydrogenation of phenylacetylene to styrene, and diphenylacetylene to diphenylethane passing through the stilbene stage.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 971–975, May, 1976.
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Borunova, N.V., Antonov, P.G., Kukushkin, Y.N. et al. Investigation of the catalytic properties of platinum-tin complexes containing dimethyl sulfoxide, dimethylformamide, or dimethylacetamide. Russ Chem Bull 25, 948–952 (1976). https://doi.org/10.1007/BF00921970
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DOI: https://doi.org/10.1007/BF00921970