Stability of rare-earth tetrafluorides

  • Yu. M. Kiselev
  • V. G. Sevast'yanov
  • V. I. Spitsyn
Inorganic Chemistry


  1. 1.

    According to thermogravimetric data, PrF4, decomposes when heated, with evolution of fluorine, as in the case of CeF4 and TbF4.

  2. 2.

    The authors have measured the vapor pressure of the fluorine formed by thermolysis of rare-earth tetrafluorides, and have calculated the thermodynamic characteristics of these tetrafluorides.



Vapor Pressure Fluorine Thermolysis Thermodynamic Characteristic CeF4 
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Literature cited

  1. 1.
    V. I. Spitsyn, Yu. M. Kiselev, and L. I. Martynenko, Zh. Neorgan. Khimii,19, 1152 (1974).Google Scholar
  2. 2.
    V. I. Spitsyn, Yu. M. Kiselev, L. I. Martynenko, V. N. Prusakov, and V. B. Sokolov, Dokl. Akad. Nauk SSSR,219, 621 (1974).Google Scholar
  3. 3.
    B. B. Cunningham, D. C. Feay, and M. A. Rollier, J. Amer. Chem. Soc.,76, 3361 (1954).Google Scholar
  4. 4.
    L. R. Batsanova, Yu. V. Zakhar'ev, and A. A. Opalovskii, Zh. Neorgan. Khimii,18, 965 (1973).Google Scholar
  5. 5.
    V. I. Spitsyn, Yu. M. Kiselev, and L. I. Martynenko, Zh. Neorgan. Khimii,19, 3194 (1974).Google Scholar
  6. 6.
    Yu. M. Kiselev, L. I. Martynenko, and V. I. Spitsyn, Zh. Neorgan. Khimii,20, 1788 (1975).Google Scholar
  7. 7.
    T. V. Meshcheryakova and N. D. Topor, Vestn. Mosk. un-ta, Ser. Khimiya, No. 3, 73 (1967).Google Scholar
  8. 8.
    H. H. Gorowitz and G. Metzger, Anal. Chem.,35, 1464 (1963).Google Scholar
  9. 9.
    T. N. Rezukhina, E. G. Ippolitov, L. I. Kholokholova, and T. S. Sysoeva, Abstracts of Reports to the Fourth All-Union Symposium on the Chemistry of Inorganic Fluorides [in Russian], Dushanbe (1975), p. 127.Google Scholar
  10. 10.
    T. N. Rezukhina (Resukhina), T. F. Sysoeva (Sisoeva), L. I. Kholokholova (Holokholova), and E. G. Ippolitov, J. Chem. Thermodyn., 883 (1974).Google Scholar
  11. 11.
    V. N. Prusakov and V. B. Sokolov, At. Énerg.,31, 259 (1971).Google Scholar
  12. 12.
    L. B. Asprey and B. B. Cunningham. Progress in Inorg. Chem.,2, 267 (1966).Google Scholar
  13. 13.
    Halogen Chem., Academic Press, New York-London (1967), Vol. 1, p. 206.Google Scholar
  14. 14.
    F. Spedding, B. J. Beaudry, D. C. Henderson, and J. Moorman, J. Chem. Phys.,60, 1578 (1974).Google Scholar
  15. 15.
    L. J. Nugent, R. D. Baybarz, J. L. Burnett, and J. L. Ryan, J. Inorg. and Nucl. Chem.,33, 2503 (1971).Google Scholar

Copyright information

© Plenum Publishing Corporation 1976

Authors and Affiliations

  • Yu. M. Kiselev
    • 1
    • 2
  • V. G. Sevast'yanov
    • 1
    • 2
  • V. I. Spitsyn
    • 1
    • 2
  1. 1.N. S. Kurnakov Institute of General and Inorganic ChemistryAcademy of Sciences of the USSRMoscow
  2. 2.M. V. Lomonosov Moscow State UniversityUSSR

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