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Effect of composition of binary palladium alloys on direction of catalytic transformations of 1,2-cyclohexanediol

  • M. E. Sarylova
  • A. P. Mishchenko
  • V. M. Gryaznov
  • V. S. Smirnov
Brief Communications

Conclusions

A study of the binary alloys of Pd with Ni, Ti, Cu, and Rh as regards the transformations of 1, 2-cyclohexanediol disclosed that the character of the products is strongly dependent on the nature of the second component of the alloy. Cyclohexanone and phenol predominate in the products obtained on the binary Pd alloys that contain Ni, Ti, or Cu, while the Pd-Rh alloys are selective catalysts for the dehydrogenation of 1,2-cyclohexanediol to pyrocatechol without forming phenol.

Keywords

Phenol Palladium Dehydrogenation Binary Alloy Cyclohexanone 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

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Copyright information

© Plenum Publishing Corporation 1977

Authors and Affiliations

  • M. E. Sarylova
    • 1
    • 2
  • A. P. Mishchenko
    • 1
    • 2
  • V. M. Gryaznov
    • 1
    • 2
  • V. S. Smirnov
    • 1
    • 2
  1. 1.A. V. Topchiev Institute of Petrochemical SynthesisAcademy of Sciences of the USSRMoscow
  2. 2.P. Lumumba Moscow International Friendship UniversityMoscow

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