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Stepwise telomerization of 1-alkenes with diethyl dibromomalonate: Formation of spirodilactones

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

Homolytic interactions of diethyldibromomalonate with 1-alkenes proceeds in two directions: a) formation of adducts, and b) stepwise telomerization, accompanied by radical chain lactonization resulting in the formation of spirodilactones of bis(2-hydroxyalkyl)malonic acids.

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Authors and Affiliations

  1. Institute of Heterorganic compounds, Academy of Sciences of the USSR, Moscow

    F. K. Velichko, R. A. Amriev, T. A. Pudova & R. Kh. Freidlina

Authors
  1. F. K. Velichko
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  2. R. A. Amriev
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  3. T. A. Pudova
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  4. R. Kh. Freidlina
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 369–372, 1977.

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Velichko, F.K., Amriev, R.A., Pudova, T.A. et al. Stepwise telomerization of 1-alkenes with diethyl dibromomalonate: Formation of spirodilactones. Russ Chem Bull 26, 330–333 (1977). https://doi.org/10.1007/BF00921844

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  • DOI: https://doi.org/10.1007/BF00921844

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