Conclusions
The strength of intramolecular hydrogen bonding in the o-(aminomethyl)phenols varies by some 5 kcal/mole, depending on the substituent at the nitrogen atom and in the benzene ring. Steric effects from the substituent determine the bonding strength.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 331–334, February, 1977.
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Belskii, V.E., Kudryavtseva, L.A., Shishkina, N.A. et al. Intramolecular hydrogen bonding in the o-(aminomethyl) phenols. Russ Chem Bull 26, 294–297 (1977). https://doi.org/10.1007/BF00921835
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DOI: https://doi.org/10.1007/BF00921835