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Tetraalkylammonium haloperchloratoaluminates

  • Inorganic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    By direct reaction between ionic perchlorates and AlX3 (X = Cl, Br), the Cl04, group can be introduced into the coordination sphere of the aluminum atom.

  2. 2.

    The authors have synthesized the stable complexes R4N+[X3AlOCl03]− (R = CH3, C2H5, C4, H9; X = Cl, Br). These complexes have sharp melting points, which decrease as we go from X = Cl to X = Br and from R = CH3 to R = C4H9.

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Authors and Affiliations

  1. Institute of New Chemical Problems, Academy of Sciences of the USSR, Chernogolovka

    K. V. Titova & E. I. Kolmakova

Authors
  1. K. V. Titova
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  2. E. I. Kolmakova
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 263–266, February, 1977.

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Titova, K.V., Kolmakova, E.I. Tetraalkylammonium haloperchloratoaluminates. Russ Chem Bull 26, 229–231 (1977). https://doi.org/10.1007/BF00921820

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  • DOI: https://doi.org/10.1007/BF00921820

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