Conclusions
A synthetic procedure for the production of the ketals of cis- and trans-geranylacetones with cis- and trans-CD3 groups at the C-2 atom was studied.
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M. T. Mustafaeva, V. A. Smit, A. V. Semenovskii, V. A. Kuzovkin, and V. F. Kucherov, Izv. Akad. Nauk SSSR, Ser. Khim., 384 (1973).
E. E. van Tamelen and T. J. Curphey, Tetrahedron Lett., 121 (1962).
R. J. Anderson, C. A. Henrick, J. B. Siddal, and R. Zurfluh, J. Am. Chem. Soc.,94, 5379 (1972).
W. E. Bondinell, C. D. Snyder, and H. Rapoport, J. Am. Chem. Soc.,9l, 6889 (1969).
O. Isler, H. Gutmann, M. Montavon, R. Rüegg, G. Ryser, and P. Zeller, Helv. Chim. Acta,40, 1242 (1957).
H. J. Bestmann and H. Schulz, Chem. Ber.,95, 2921 (1962).
C. A. Buehler and D. E. Pearson, Survey of Organic Syntheses, Wiley-mterscience (1970).
G. Stork, P. A. Grieco, and M. Gregson, Tetrahedron Lett., 1393 (1969).
E. H. Axelrod, G. M. Milne, and E. E. van Tamelen, J. Am. Chem. Soc.,92, 2139 (1970).
E. E. Gilbert and H. R. Nychka, US Patent 2928836; Chem. Abstr.,54, 12165a (1960).
E. J. Corey and K. Achiwa, J. Org. Chem.,34, 3667 (1969).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2074–2077, September, 1976.
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Mizyuk, V.L., Semenovskii, A.V. The stereospecific introduction of a label into the terminal methyl group in an isoprenoid molecule in the case of isomeric geranylacetones-d3 . Russ Chem Bull 25, 1943–1947 (1976). https://doi.org/10.1007/BF00921726
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DOI: https://doi.org/10.1007/BF00921726