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The photochemistry of aliphatic nitro compounds

4. Flash photolysis of chlorotrinitromethane solutions
  • V. P. Balykin
  • V. I. Slovetskii
  • E. M. Maksyutov
Physical Chemistry
  • 19 Downloads

Conclusions

  1. 1.

    The primary act in the flash photolysis of chlorotrinitromethane in alcoholic solvents is the formation of chlorodinitromethane anions.

     
  2. 2.

    The principal direction of the photochemical reaction in alcoholic solvents is that leading to chlorotrinitromethane breakdown by an ionic mechanism.

     
  3. 3.

    The formation of chlorodinitromethane anions is a first-order process. The rate of this reaction varies in passing from one solvent to another.

     
  4. 4.

    The chlorodinitromethane anions resulting from the photolysis of chlorotrinitromethane in alcoholic solvents are quite reactive and are consumed in secondary processes. The final products from these reactions are dichlorodinitromethane and nitroform anions.

     

Keywords

Photolysis Photochemical Reaction Principal Direction Nitro Compound Secondary Process 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1977

Authors and Affiliations

  • V. P. Balykin
    • 1
  • V. I. Slovetskii
    • 1
  • E. M. Maksyutov
    • 1
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of Sciences of the USSRMoscow

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