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Intermediate product of 2,4,6-tri-tert-butyl-p-quinofluoride photolysis

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

Proof is presented to support the fact that the intermediate product of 2,4,6-tritert-butyl-p-quinofluoride photolysis is a biradical that is formed by the intramolecular reduction of the CO group. The biradical rakes part in the acid-base equilibrium to form the protonated oxygen form.

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Literature cited

  1. I. Ya. Aliev, I. N. Rozhkov, and I. L. Knunyants, Izv. Akad. Nauk SSSR, Ser. Khim.,1974, 2390.

  2. E. Hayon, T. Ibata, N. N. Linchtin, and M. Simic, J. Phys. Chem.,76, 2072 (1972).

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow

    I. V. Khudyakov, I. Ya. Aliev & V. A. Kuz'min

Authors
  1. I. V. Khudyakov
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  2. I. Ya. Aliev
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  3. V. A. Kuz'min
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2598–2600, November, 1975.

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Khudyakov, I.V., Aliev, I.Y. & Kuz'min, V.A. Intermediate product of 2,4,6-tri-tert-butyl-p-quinofluoride photolysis. Russ Chem Bull 24, 2487–2488 (1975). https://doi.org/10.1007/BF00921676

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  • DOI: https://doi.org/10.1007/BF00921676

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