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Cleavage of o-carboranes to (3)-l,2-dicarbaundecarborates by amines

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

When the cleavage rate of some C-substituted o-carboranes to the (3)-l,2-dicarbaunde-carborate anion by treatment with amines was studied it was established that the reaction is first order in both the o-carborane and the amine. The cleavage rate depends on the nature of the amine and the nature of the substituent in the o-carborane.

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Literature cited

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2596–2598, November, 1975.

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Zakharkin, L.I., Kirillova, V.S. Cleavage of o-carboranes to (3)-l,2-dicarbaundecarborates by amines. Russ Chem Bull 24, 2484–2486 (1975). https://doi.org/10.1007/BF00921675

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  • DOI: https://doi.org/10.1007/BF00921675

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