Rearrangement of 1-allyl-o-carboranes to trans-1-propenyl-o-carboranes by bases

  • L. I. Zakharkin
  • N. N. Ivanova
Brief Communications
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Conclusions

  1. 1.

    Under the influence of strong bases the 1-allyl-o-carboranes isomerize completely to the trans-1-propenyl-o-carboranes.

     
  2. 2.

    We determined the kinetic parameters of the isomerization of 1-ally1-2-isopropyl-o-carborane to l-propenyl-2-isopropyl-o-carborane under the influence of (CH3)3COK in (CH3)3- COH solution.

     

Keywords

Kinetic Parameter Strong Basis 

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Literature cited

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    D. Cram, Principles of the Chemistry of Carbanions [Russian translation], Mir (1967).Google Scholar
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    L. I. Zakharkin, V. N. Kalinin, and A. P. Snyakin, Zh. Obshch. Khim.,40, 2424 (1970).Google Scholar
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    D. H. Hunter and D. J. Cram, J. Am. Chem. Soc,86, 5478 (1964).Google Scholar
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    L. I. Zakharkin, S. A. Babich, L. E. Litovchenko, and N. N. Ivanova, Zh. Obshch. Khim.,43, 2389 (1973).Google Scholar

Copyright information

© Plenum Publishing Corporation 1976

Authors and Affiliations

  • L. I. Zakharkin
    • 1
  • N. N. Ivanova
    • 1
  1. 1.Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRMoscow

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