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Rearrangement of 1-allyl-o-carboranes to trans-1-propenyl-o-carboranes by bases

  • L. I. Zakharkin
  • N. N. Ivanova
Brief Communications

Conclusions

  1. 1.

    Under the influence of strong bases the 1-allyl-o-carboranes isomerize completely to the trans-1-propenyl-o-carboranes.

     
  2. 2.

    We determined the kinetic parameters of the isomerization of 1-ally1-2-isopropyl-o-carborane to l-propenyl-2-isopropyl-o-carborane under the influence of (CH3)3COK in (CH3)3- COH solution.

     

Keywords

Kinetic Parameter Strong Basis 
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Literature cited

  1. 1.
    D. Cram, Principles of the Chemistry of Carbanions [Russian translation], Mir (1967).Google Scholar
  2. 2.
    D. E. O'Connor and W. I. Lyness, J. Am. Chem. Soc.,86, 3840 (1964).Google Scholar
  3. 3.
    L. I. Zakharkin, V. N. Kalinin, and A. P. Snyakin, Zh. Obshch. Khim.,40, 2424 (1970).Google Scholar
  4. 4.
    D. H. Hunter and D. J. Cram, J. Am. Chem. Soc,86, 5478 (1964).Google Scholar
  5. 5.
    L. I. Zakharkin, S. A. Babich, L. E. Litovchenko, and N. N. Ivanova, Zh. Obshch. Khim.,43, 2389 (1973).Google Scholar

Copyright information

© Plenum Publishing Corporation 1976

Authors and Affiliations

  • L. I. Zakharkin
    • 1
  • N. N. Ivanova
    • 1
  1. 1.Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRMoscow

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