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Rearrangement of 1-allyl-o-carboranes to trans-1-propenyl-o-carboranes by bases

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

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Conclusions

  1. 1.

    Under the influence of strong bases the 1-allyl-o-carboranes isomerize completely to the trans-1-propenyl-o-carboranes.

  2. 2.

    We determined the kinetic parameters of the isomerization of 1-ally1-2-isopropyl-o-carborane to l-propenyl-2-isopropyl-o-carborane under the influence of (CH3)3COK in (CH3)3- COH solution.

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Literature cited

  1. D. Cram, Principles of the Chemistry of Carbanions [Russian translation], Mir (1967).

  2. D. E. O'Connor and W. I. Lyness, J. Am. Chem. Soc.,86, 3840 (1964).

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  3. L. I. Zakharkin, V. N. Kalinin, and A. P. Snyakin, Zh. Obshch. Khim.,40, 2424 (1970).

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  5. L. I. Zakharkin, S. A. Babich, L. E. Litovchenko, and N. N. Ivanova, Zh. Obshch. Khim.,43, 2389 (1973).

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    L. I. Zakharkin & N. N. Ivanova

Authors
  1. L. I. Zakharkin
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  2. N. N. Ivanova
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2594–2596, November, 1975.

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Zakharkin, L.I., Ivanova, N.N. Rearrangement of 1-allyl-o-carboranes to trans-1-propenyl-o-carboranes by bases. Russ Chem Bull 24, 2481–2483 (1975). https://doi.org/10.1007/BF00921674

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  • DOI: https://doi.org/10.1007/BF00921674

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