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Use of liquid chromatography to study the adsorption of aqueous solutions of nitroalkanes on graphite

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The Chromatographie method was used to determine the adsorption isotherms of aqueous solutions of four nitroalkanes on graphite at 293, 308, and 323°K, and the thermo-dynamic parameters of the adsorbability were calculated.

  2. 2.

    On an unoxidized graphite surface the standard change in the enthalpy of adsorption increases with increase in the chain length of the molecule, and decreases on an oxidized surface.

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Authors and Affiliations

  1. Institute of Chemistry, Far-Eastern Scientific Center of the Academy of Sciences of the USSR, Vladivostok

    V. A. Avramenko, V. Yu. Glushchenko & E. F. Radaev

Authors
  1. V. A. Avramenko
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  2. V. Yu. Glushchenko
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  3. E. F. Radaev
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2582–2585, November, 1975.

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Avramenko, V.A., Glushchenko, V.Y. & Radaev, E.F. Use of liquid chromatography to study the adsorption of aqueous solutions of nitroalkanes on graphite. Russ Chem Bull 24, 2468–2470 (1975). https://doi.org/10.1007/BF00921669

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  • DOI: https://doi.org/10.1007/BF00921669

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