Conclusions
The thermolysis of sodium trichloroacetate in the presence of crotonaldehyde gives 1-trichloromethyl-2-buten-1-ol. Compounds that contain a cyclopropane ring are not formed under these conditions.
Literature cited
W. M. Wagner and H. Kloosterziel, Rec. Trav. Chim.,80, 740 (1961).
W. M. Wagner, H. Kloosterziel, and A. F. Bicker, Rec. Trav. Chim.,81, 925 (1962).
V. S. Aksenov, L. A. Serkina, V. M. Shostakovskii, M. I. Kravchenko, and O. M. Nefedov, Reports of Fourth All-Union Conference on Acetylene Chemistry [in Russian], Vol. 1, Izd. AN KazSSR, Alma-Ata (1972), p. 223.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2577–2579, November, 1975.
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Shostakovskii, M.F., Erofeev, V.I. & Aksenov, V.S. Unsaturated aldehydes in the thermolysis of sodium trichloroacetate. Russ Chem Bull 24, 2462–2464 (1975). https://doi.org/10.1007/BF00921667
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DOI: https://doi.org/10.1007/BF00921667