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Synthesis and chemical properties of some esters of carboranylphosphonous acids

  • Organic and Biological Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A number of esters of carboranylphosphonous and carboranylphosphonic acids was obtained.

  2. 2.

    The esters of carboranylphosphonous acids are capable of entering into the Arbuzov reaction under the influence of various electrophilic reagents.

  3. 3.

    The C-P bond is cleaved when carboranylphosphonites are reacted with water and alcohols.

  4. 4.

    The presence of the electron-acceptor carboranyl group on the phosphorus atom is reflected in a certain decrease in the reactivity of the carboranylphosphonites.

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Literature cited

  1. R. P. Alexander and H. A. Schroeder, Inorg. Chem.,5, 493 (1966).

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  2. A. V. Kazantsev, M. N. Zhubekova, and L. I. Zakharkin, Zh. Obshch. Khim.,41, 2027 (1971).

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  3. A. N. Degtyarev, N. N. Godovikov, V. I. Bregadze, and M. I. Kabachnik, Izv. Akad. Nauk SSSR, Ser. Khim.,1973, 2369.

  4. M. N. Zhubekova, Dissertation, Alma-Ata (1972).

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    N. N. Godovikov, A. N. Degtyarev, V. I. Bregadze & M. I. Kabachnik

Authors
  1. N. N. Godovikov
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  2. A. N. Degtyarev
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  3. V. I. Bregadze
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  4. M. I. Kabachnik
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2568–2573, November, 1975.

The authors express their gratitude to P. V. Petrov and V. I. Robas for taking and interpreting the NMR spectra, and to E. I. Matrosov and M. I. Volkova for taking the IR spectra.

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Godovikov, N.N., Degtyarev, A.N., Bregadze, V.I. et al. Synthesis and chemical properties of some esters of carboranylphosphonous acids. Russ Chem Bull 24, 2454–2458 (1975). https://doi.org/10.1007/BF00921665

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  • DOI: https://doi.org/10.1007/BF00921665

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