Reaction of phosphorus pentachloride with some α-hydroxy-carboxylic acids

  • L. I. Gurarii
  • É. T. Mukmenev
Organic and Biological Chemistry


The reaction of PCl5 with the D,L-malic and D-tartaric acids gives the 0-[l,2-di-(chloroformyl)ethyl] and 0-[2-chloro-l,2-di(chloroformyl)ethyl] dichlorophosphates, while reaction with dihydroxymaleic acid gives 2,2,2-trichloro-4,5-di(chloroformyl)-l,3,2-dioxa-4-phospholene.


Phosphorus Ethyl PCl5 Phosphorus Pentachloride Dichlorophosphates 
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Copyright information

© Plenum Publishing Corporation 1976

Authors and Affiliations

  • L. I. Gurarii
    • 1
  • É. T. Mukmenev
    • 1
  1. 1.A. E. Arbuzov Institute of Organic and Physical ChemistryKazan Branch of the Academy of Sciences of the USSRUSSR

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