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Fluorine-containing β-sultones

Communication 45. 2-hydropentafluoropropane-2-β-sultone

  • Organic and Biological Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    2-Hydropentafluoropropane-2-β-sultone was obtained by the sulfotrioxidation of 2-hydropentafluoropropylene.

  2. 2.

    A number of 1-sulfonyl-2, 2, 2-trifluoropropionic acid and 2, 2, 2-trifluoroethanesulfonic acid derivatives were prepared from this β-sultone.

  3. 3.

    2, 2, 2-Trifluoroethanesulfonyl fluoride and its α-mono-substituted derivatives are CH acids.

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Literature cited

  1. I. L. Knunyants and Yu. A. Cheburkov, Syntheses of Organofluorine Compounds [in Russian], Khimiya (1973), p. 14.

  2. M. A. Dmitriev, G. A. Sokol'skii, and I. L. Knunyants, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk,1960, 847.

  3. I. L. Knunyants (Knunyanz) and G. A. Sokol'skii (Sokolsky), Angew. Chem.,84, 623 (1972).

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  5. A. K. Dibrova, L. I. Kuznetsova, L. I. Ragulin, G. A. Sokol'skii, and I. L. Knunyants, Izv. Akad. Nauk SSSR, Ser. Khim.,1973, 1563.

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2530–2535, November, 1975.

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Aktaev, N.P., Sokol'skii, G.A. & Knunyants, I.L. Fluorine-containing β-sultones. Russ Chem Bull 24, 2416–2421 (1975). https://doi.org/10.1007/BF00921658

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  • DOI: https://doi.org/10.1007/BF00921658

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