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Generation of ω-carbomethoxyalkyl radicals and syntheses based on them

  • Organic and Biological Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The reaction of the esters of peroxydicarboxylic acids (CH3OOC(CH2)nCOO)2 with Fe(II) sulfate leads to the selective generation of ω-carbomethoxyalkyl radicals CH3OOC-(CH2)n, n=2-5, 7, 8, 10.

  2. 2.

    These radicals predominantly recombine under the influence of Fe(II) sulfate, while Cu(II) sulfate oxidizes them to the esters of the corresponding ω-unsaturated carboxylic acids, and Cu(II) chloride converts them to the esters of (ω-chlorocarboxylic acids.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    G. I. Nikishin, S. I. Moryasheva & E. K. Starostin

Authors
  1. G. I. Nikishin
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  2. S. I. Moryasheva
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  3. E. K. Starostin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2501–2505, November, 1975.

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Nikishin, G.I., Moryasheva, S.I. & Starostin, E.K. Generation of ω-carbomethoxyalkyl radicals and syntheses based on them. Russ Chem Bull 24, 2387–2391 (1975). https://doi.org/10.1007/BF00921653

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  • DOI: https://doi.org/10.1007/BF00921653

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