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Telomerization of propylene with carboxylic acids

  • Organic and Biological Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The telomerization of propylene with isobutyric and propionic acids were studied.

  2. 2.

    The partial chain transfer constants in the telomerization of propylene with isobutyric acid are substantially higher than in the reaction of carboxylic acids with ethylene.

  3. 3.

    The telomerization of propylene with propionic acid goes with rearrangement of the radicals, which includes a 1,3-migration of the H atom.

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Literature cited

  1. R. Kh. Freidlina, P. A. Zagorets, I. N. Bryantsev, and A. B. Terent'ev, Dokl. Akad. Nauk SSSR,197, 105 (1971).

    Google Scholar 

  2. A. B. Terent'ev, N. S. Ikonnikov, V. I. Dostovalova, and R. Kh. Freidlina, Dokl. Akad. Nauk SSSR,213, 1345 (1973).

    Google Scholar 

  3. N. S. Ikonnikov and A. B. Terent'ev, Izv. Akad. Nauk SSSR, Ser. Khim.,1975, 371.

  4. A. B. Terent'ev, M. A. Churilova, N. S. Ikonnikov, and R. Kh. Freidlina, Izv. Akad. Nauk SSSR, Ser. Khim.,1975, 439.

  5. J. Iyoda, J. Souma, and H. Sano, Osaka Kogyo Gijutsu Shikensho Kiho,23, 197 (1972).

    Google Scholar 

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    M. A. Churilova, D. I. Povolotskii & A. B. Tarent'ev

Authors
  1. M. A. Churilova
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  2. D. I. Povolotskii
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  3. A. B. Tarent'ev
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2497–2501, November, 1975.

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Churilova, M.A., Povolotskii, D.I. & Tarent'ev, A.B. Telomerization of propylene with carboxylic acids. Russ Chem Bull 24, 2382–2386 (1975). https://doi.org/10.1007/BF00921652

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  • DOI: https://doi.org/10.1007/BF00921652

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