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Vibrational and electronic spectra of α- and β-trialkyl-silylacroleins

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The IR and UV spectra of α- and β-trialkylsilylacroleins were studied. The influence of the trialkylsilyl substituent on the system of conjugated bonds C=C-C=0 in the ground and excited states of the molecule is transmitted both according to an inductive and according to a resonance mechanism of the type dπ-pπ interaction.

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Authors and Affiliations

  1. Irkutsk Institute of Organic Chemistry, Siberian Branch of the Academy of Sciences of the USSR, USSR

    M. G. Voronkov, S. V. Kirpichenko, V. V. Keiko & L. V. Sherstyannikova

Authors
  1. M. G. Voronkov
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  2. S. V. Kirpichenko
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  3. V. V. Keiko
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  4. L. V. Sherstyannikova
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2471–2474, November, 1975.

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Voronkov, M.G., Kirpichenko, S.V., Keiko, V.V. et al. Vibrational and electronic spectra of α- and β-trialkyl-silylacroleins. Russ Chem Bull 24, 2357–2360 (1975). https://doi.org/10.1007/BF00921647

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  • DOI: https://doi.org/10.1007/BF00921647

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