Skip to main content
SpringerLink
Log in

Production of cesium hexaperchloratotitanate by the reaction of titanium perchlorate with cesium perchlorate

  • Inorganic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Titanium perchlorate in anhydrous perchloric acid medium with the formation of cesium hexaperchloratotitanate Cs2 [Ti(ClO4 6)]. Complexes with a ratio CsClO4:Ti(ClO4)4>2 are not formed.

  2. 2.

    On the basis of the IR spectra, a conclusion was drawn on a change in the mode of coordination of the perchlorato groups from bidentate in the Ti(ClO4)4 molecule to monodentate in the [Ti(ClO4)6]2− anion.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. V. P. Babaeva and V. Ya. Rosolovskii, Izv. Akad. Nauk SSSR, Ser. Khim., 2414 (1974).

  2. Z. K. Nikitina, A. I. Karelin, and V. Ya. Rosolovskii, Izv. Akad. Nauk SSSR, Ser. Khim., 723 (1973).

  3. Z. K. Nikitina, A. I. Karelin, and V. Ya. Rosolovskii, Izv. Akad. Nauk SSSR, Ser. Khim., 971 (1973).

  4. K. W. Bagnall, D. Brown, and J. G. H. du Preez, J. Chem. Soc., 5523 (1964).

  5. V. Ya. Rosolovskii, Chemistry of Anhydrous Perchloric Acid [in Russian], Nauka (1966).

  6. V. P. Babaeva and V. Ya. Rosolovskii, Izv. Akad. Nauk SSSR, Ser. Khim. 494 (1973).

  7. S. K. Syal and S. P. Yoganarasimham, Inorg. Nucl. Chem. Letters,9, 1193 (1973).

    Google Scholar 

  8. L. B. Serezhkina, Z. I. Grigorovich, I. A. Karelin, N. S. Tamm, and A. V. Novoselova, Dokl. Akad. Nauk SSSR,206, 634 (1972).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Academy of Sciences of the USSR, Moscow

    V. P. Babaeva & V. Ya. Rosolovskii

Authors
  1. V. P. Babaeva
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. Ya. Rosolovskii
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2393–2396, November, 1975.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Babaeva, V.P., Rosolovskii, V.Y. Production of cesium hexaperchloratotitanate by the reaction of titanium perchlorate with cesium perchlorate. Russ Chem Bull 24, 2278–2281 (1975). https://doi.org/10.1007/BF00921631

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00921631

Keywords

Search

Navigation