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Reaction of conjugated dienes with trimethyldeuterosilane

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

A study was made of the reaction of butadiene, isoprene, and 3-methyl-1,4,6-heptatriene with trimethyldeuterosilane, and the location of the deuterium atom in the alkenylsilane molecule was established on the basis of the1H and13C NMR spectral data, and also the mass-spectral data for dissociative electron capture. A scheme was proposed for the hydrosilylation process.

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 204–208, January, 1977.

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Yur'ev, V.P., Salimgareeva, I.M., Zhebarov, O.Z. et al. Reaction of conjugated dienes with trimethyldeuterosilane. Russ Chem Bull 26, 181–184 (1977). https://doi.org/10.1007/BF00921526

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  • DOI: https://doi.org/10.1007/BF00921526

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