Conclusions
The following reactions were effected in the presence of the coordination initiators Fe(CO)5 + i-C3H7OH (or Hexametapol): a) Telomerization of vinyl chloride with 1,1,1-trichloropropane and 1,1,1,3,3-pentachloropropane. Telomers that contain 1–3 monomeric units in the molecule were isolated, b) The addition of 1,1,1,3-tetrachloropropane and 1,1,1-trichloroethane to isobutylene; the adducts were obtained in good yields, c) The reaction of allyl chloride with 1,1,1,3-tetrachloropropane, which leads to the formation of the adduct and by-products as the result of the partial fragmentation of the ClCH2CH2CCl2CH2CHCH2Cl radicals with the cleavage of chlorine atom.
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Literature cited
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 174–177, January, 1977.
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Freidlina, R.K., Kuz'mina, N.A., Kamyshova, A.A. et al. Reaction of gem-trichloroalkanes with unsaturated compounds in presence of Fe(CO)5 and a cocatalyst. Russ Chem Bull 26, 151–154 (1977). https://doi.org/10.1007/BF00921516
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DOI: https://doi.org/10.1007/BF00921516