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Formation of charge-transfer complexes by reaction of amines, alcohols, and olefins with metal carbonyls

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Employing UV spectroscopy it was shown that when reacted with metal carbonyls the tendency to form charge-transfer complexes increases in the order: olefin < alcohol < amine, which is in harmony with a weakening of their basicity and electron-donor properties.

  2. 2.

    The addition of an alkyl halide increases the polarization of the electron-donor ligand in the complex with the metal carbonyl.

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Literature cited

  1. J. Falbe, Syntheses Based on Carbon Monoxide in Organic Synthesis, Springer-Verlag (1970).

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    B. K. Nefedov & V. A. Petukhov

Authors
  1. B. K. Nefedov
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  2. V. A. Petukhov
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 172–174, January, 1977.

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Nefedov, B.K., Petukhov, V.A. Formation of charge-transfer complexes by reaction of amines, alcohols, and olefins with metal carbonyls. Russ Chem Bull 26, 149–151 (1977). https://doi.org/10.1007/BF00921515

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  • DOI: https://doi.org/10.1007/BF00921515

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