Conclusions
-
1.
The bond energy of the 2p electrons of phosphorus decreases in the x-ray photoelectronic spectra during the fusion of phosphonic acids, possibly due to a decrease in the P...OH interactions between the atoms of adjacent molecules.
-
2.
It was shown by the PMR and x-ray methods that a difference exists in the packing of the molecules in the unit cell of phosphonic acids and phosphates.
Literature cited
M. Pelavin, D. N. Nendricson, J. M. Hollander, and W. L. Jolly, J. Phys. Chem.,74, 1118 (1970).
W. E. Morgan, J. R. van Wazer, and W. J. Stec, J. Am. Chem. Soc.,95, 751 (1970).
B. J. Lindberg and J. Hedman, Chem. Scripta,1, 155 (1975).
G. W. Svetich and C. N. Caughan, Acta Cryst.,19, 645 (1965).
G. M. Kosolapoff, Organophospherus Compounds, Wiley, New York-London (1950), pp. 148, 162, 256.
D. Purdela and R. Vylchanu, Chemistry of Organic Phosphorus Compounds [Russian translation], Khimiya (1972), pp. 400, 524.
V. A. Trapeznikov, V. I. Povstugar, A. V. Evstaf'ev, and V. P. Sapozhnikov, Abstracts of Papers of International Symposium “X-ray Photoelectronic Spectroscopy” [in Russian], ONTI IMF ANUkrSSR, Kiev (1975), p. 60.
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 165–167, January, 1977.
Rights and permissions
About this article
Cite this article
Kodolov, V.I., Povstugar, V.I., Alyamovskii, S.I. et al. Study of changes in phosphonic and phosphoric fragments during fusion of some phosphorus acids. Russ Chem Bull 26, 142–143 (1977). https://doi.org/10.1007/BF00921512
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00921512