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Partial synthesis of 20 (R),22 (R)-δ5-cholestene-3β,20,22, triol

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusion

  1. 1.

    The synthesis of 3β-acetoxy-20-hydroxy-Δ5-bisnorchoIenealdehyde (VII), the starting material for the synthesis of ecdysone-related compounds, was accomplished.

  2. 2.

    Starting with (VII), the isomeric Δ5-cholestene-3β,20,22-triols (I and XI) were obtained by the Grignard reaction.

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Authors and Affiliations

  1. M. M. Shemyakin Institute of Bioorganic Chemistry, Academy of Sciences of the USSR, Moscow

    Zh. S. Sydykov & G. M. Segal'

Authors
  1. Zh. S. Sydykov
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  2. G. M. Segal'
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Translated from Izvestiya Akademii Nauk, SSSR, Seriya Khimiya, No. 1, pp. 161–165, January, 1977.

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Sydykov, Z.S., Segal', G.M. Partial synthesis of 20 (R),22 (R)-δ5-cholestene-3β,20,22, triol. Russ Chem Bull 26, 138–141 (1977). https://doi.org/10.1007/BF00921511

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  • DOI: https://doi.org/10.1007/BF00921511

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