Reaction of the carbonyls of group VI metals with benzonitrile and ω-cyanoalkylbenzenes

  • A. N. Nesmeyanov
  • V. S. Kaganovich
  • V. V. Krivykh
  • M. I. Rybinskaya
Organic Chemistry

Conclusions

  1. 1.

    Complexes of the RCN·M(CO)5 type (where M=Cr, Mo, and W) are formed during the photochemical reaction of group VI metal carbonyls with arene-containing nitriles, whereas (CO)3Cr·Ph(CH2)nCN complexes with coordination in the arene nucleus (n=0–3) are obtained during the thermal reaction in the case of chromium.

     
  2. 2.

    Binuclear complexes containing molybdenum and tungsten attached to a common organic ligand were obtained by the reaction of the Ar(CH2)3CN· W(CO)5 complexes with Py3Mo(CO)3.

     
  3. 3.

    The photochemical transformations of the obtained chromium tricarbonyl π complexes of the eyanoalkylbenzenes were studied.

     

Keywords

Chromium Tungsten Carbonyl Molybdenum Nitrile 

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Literature cited

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Copyright information

© Plenum Publishing CorporationPlenum Publishing Corporation 1977

Authors and Affiliations

  • A. N. Nesmeyanov
    • 1
  • V. S. Kaganovich
    • 1
  • V. V. Krivykh
    • 1
  • M. I. Rybinskaya
    • 1
  1. 1.Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRMoscow

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