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Stereoselective reduction of gem-dichlorocyclopropyl ethers

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    We have studied the partial and complete LiAlH4 reduction of gem-dichlorocyclopropyl ethers to 2-chlorocyclopropyl and cyclopropyl ethers.

  2. 2.

    In the partial reduction of gem-dichlorocyclopropyl ethers the chlorine atom cis to the substituent is selectivity reduced.

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Authors and Affiliations

  1. Irkutsk Institute of Organic Chemistry, Siberian Branch of the Academy of Sciences of the USSR, USSR

    S. M. Shostakovskii, T. K. Voropaeva, N. S. Nikol'skii, A. A. Retinskii & O. B. Bannikova

Authors
  1. S. M. Shostakovskii
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  2. T. K. Voropaeva
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  3. N. S. Nikol'skii
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  4. A. A. Retinskii
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  5. O. B. Bannikova
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 125–131, January, 1977.

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Shostakovskii, S.M., Voropaeva, T.K., Nikol'skii, N.S. et al. Stereoselective reduction of gem-dichlorocyclopropyl ethers. Russ Chem Bull 26, 107–112 (1977). https://doi.org/10.1007/BF00921504

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  • DOI: https://doi.org/10.1007/BF00921504

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