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Sulfate group polarization and polarizability and the conformations of the dimethyl sulfates

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Polarity and polarizability parameters have been determined for the sulfate group.

  2. 2.

    In solution, the dimethylsulfate molecule shows trans-trans conformation of the C-O-S-O-C chain.

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Literature cited

  1. R. A. Pethrick, E. Wyn-Jones, P. C. Hamblin, and R. F. M. White, J. Chem. Soc., A, 2552 (1969).

    Google Scholar 

  2. G. Wood, J. M. Mclntosh, and M. Miskow, Tetrahedron Lett., 4895 (1970).

  3. C. Altona, M. J. Geise, and C. Romers, Rec. Trav. Chim.,85, 1197 (1966).

    Google Scholar 

  4. V. A. Naumov, V. G. Dashevskii, and N. M. Zaripov, Dokl. Akad. Nauk SSSR,185, 604 (1969).

    Google Scholar 

  5. B. V. Ioffe, Refractometric Methods in Chemistry [in Russian], Khimiya (1974).

  6. M. Tamres and S. Searles, J. Am. Chem. Soc.,81, 2100 (1959).

    Google Scholar 

  7. A. B. Remizov and G. G. Butenko, Zh. Prikl. Spektrosk., No. 7356-73 Dep. (1973).

  8. K. O. Christe and E. C. Curtis, Spectrochim. Acta,28A, 1889 (1972).

    Google Scholar 

  9. Yu. Ya. Borovikov, Yu. P. Egorov, A. M. Pinchuk, and T. A. Khimchenko, Zh. Obshch. Khim.,43, 2476 (1973).

    Google Scholar 

  10. A. B. Demptster, K. Price, and N. Sheppard, Spectrochim. Acta,25A, 138 (1969).

    Google Scholar 

  11. L. K. Yuldasheva, A. P. Timosheva, A. B. Remizov, G. N. Sergeeva, A. A. Fishman, and A. N. Vereshchagin, Izv. Akad. Nauk SSSR, Ser. Khim., 318 (1974).

  12. B. A. Arbusov, S. G. Wulf'son, (Vul'fson), and R. P. Arshinova, Phosphorus,4, 221 (1974).

    Google Scholar 

  13. J. S. Brimacombe, A. B. Foster, E. B. Hancock, W. G. Overend, and M. Stacey, J. Chem. Soc., 201 (1960).

  14. J. Lichtenberger and R. Lichtenberger, Bull. Soc. Chim. France, 1002 (1948).

  15. J. Lichtenberger and J. Hincky, Bull. Soc. Chim. France, 1495 (1961).

  16. J. J. Miller, J. Org. Chem.,27, 2680 (1962).

    Google Scholar 

  17. L. F. Wiggins, C. Beard, and J. W. James, British Patent No. 94406, Chem. Abstrs.,60, 5398h (1964).

    Google Scholar 

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 98–100, January, 1977. Original article submitted November 24, 1975.

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Klimovitskii, E.N., Yuldasheva, L.K., Vereshchagin, A.N. et al. Sulfate group polarization and polarizability and the conformations of the dimethyl sulfates. Russ Chem Bull 26, 83–85 (1977). https://doi.org/10.1007/BF00921498

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  • DOI: https://doi.org/10.1007/BF00921498

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