Conclusions
-
1.
Equilibrium constants have been obtained for deprotonation and dimerization of phenylmercury aqua ions in aqueous solution.
-
2.
Thermodynamic parameters have been calculated for the reactions of phenylmercury with Cl−, Br−, I−, SCN−, CN−, N3 −, NO2 −, p-NH2C6H4SO3 − anions in aqueous solution.
Similar content being viewed by others
Literature cited
R. Pearson, Usp. Khim.,11, 1259 (1971).
R. B. Simpson, J. Am. Chem. Soc.,83, 4711 (1961).
G. Schwarzenbach and M. Schellenberg, Helv. Chim. Acta,48, 28 (1965).
I. P. Beletskaya, K. P. Butin, A. N. Ryabtsev, and O. A. Reutov, J. Organometall. Chem.,59, 1 (1973).
K. P. Butin, I. P. Beletskaya, A. N. Ryabtsev, and O. A. Reutov, Élektrokhimiya,3, 1318 (1967).
T. Waugh, H. F. Walton, and J. A. Laswick, J. Phys. Chem.,59, 395 (1955).
L. G. Makarova and A. N. Nesmeyanov, Methods of Heteroorganic Chemistry. Mercury [in Russian], Nauka (1965), p. 332.
F. Basolo and R. G. Pearson, Mechanisms of Inorganic Reactions, Wiley-Interscience (1967).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 80–83, January, 1977.
The authors are indebited to I. P. Beletskaya for valuable advice.
Rights and permissions
About this article
Cite this article
Giuashvili, I.I., Katsman, L.A. & Vargaftik, M.N. Equilibria in the complexing of the phenylmercury cation with anion ligands in aqueous solution. Russ Chem Bull 26, 66–69 (1977). https://doi.org/10.1007/BF00921494
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00921494