Skip to main content
SpringerLink
Log in

Reactions of cumylperoxy radicals with diethylene glcol dicaprylate and pentaerythrite tetravalerate

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Rate constants have been determined for the reactions of cumyl peroxide radicals with diethylene glycol dicaprylate and pentaerythrite tetravalerate by measuring the rates of oxidation of these in the presence of cumyl peroxide.

  2. 2.

    An additive scheme of calculating reactivities from known values of partial rate constants is not applicable to reactions of cumyl peroxide radicals with polyatomic esters.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. E. T. Denisov, N. I. Mitskevich, and V. E. Agabekov, Mechanism of Liquid-Phase Oxidation of Oxygen-Containing Compounds [in Russian], Nauka i Tekhnika, Minsk (1975), pp. 193, 267–269, 296, 307–309.

    Google Scholar 

  2. G. G. Agliullina, V. S. Martem'yanov, E. T. Denisov, O. A. Kulagina, and M. M. Kukovitskii, Neftekhimiya,16, 262 (1976).

    Google Scholar 

  3. A. Weissberger, E. Proskauer, et al., Organic Solvents [Russian translation], Il (1968), p. 387.

  4. L. N. Denisova and E. T. Denisov, Kinet. Katal.,10, 1244 (1969).

    Google Scholar 

  5. N. V. Zolotova and L. L. Gervits, Neftekhimiya,15, 146 (1975).

    Google Scholar 

  6. V. L. Antonovskii, E. T. Denison, and L. V. Solntsev, Kinet. Katal.,6, 815 (1965).

    Google Scholar 

  7. J. A. Howard, W. J. Schwalm, and K. U. Ingold, Adv. Chem. Ser.,75, 6 (1968).

    Google Scholar 

  8. J. R. Thomas and C. A. Tolman, J. Am. Chem. Soc.,84, 2079 (1962).

    Google Scholar 

  9. D. G. Hendry, J. Am. Chem. Soc.,89, 5433 (1967).

    Google Scholar 

  10. J. A. Howard and S. Korcek, Can. J. Chem.,48, 2165 (1970).

    Google Scholar 

  11. J. A. Howard, Adv. Free-Radical Chem.,7, 49 (1971).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Branch of the Institute of Chemical Physics of the Academy of Sciences of the USSR, Chernogolovka

    G. G. Agliullina, V. S. Martem'yanov, E. T. Denisov & T. I. Eliseeva

  2. Bashkir State University, Ufa

    G. G. Agliullina, V. S. Martem'yanov, E. T. Denisov & T. I. Eliseeva

Authors
  1. G. G. Agliullina
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. S. Martem'yanov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. E. T. Denisov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. T. I. Eliseeva
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya, Khimicheskaya, No. 1, pp. 50–57, January, 1977.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Agliullina, G.G., Martem'yanov, V.S., Denisov, E.T. et al. Reactions of cumylperoxy radicals with diethylene glcol dicaprylate and pentaerythrite tetravalerate. Russ Chem Bull 26, 40–45 (1977). https://doi.org/10.1007/BF00921489

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00921489

Keywords

Search

Navigation