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1-ethynyl-3-chloromethyltetramethyldisiloxane and some of its reactions

  • O. G. Yarosh
  • T. D. Burnashova
  • M. G. Voronkov
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  • 22 Downloads

Conclusions

The cohydrolysis of CH ≡ CSi(CH3)2OC2H5 with ClSi(CH3)2CH2Cl gave the previously unknown 1-ethynyl-3-chloromethyltetramethyldisiloxane. The bromomagnesium derivatives of the latter were reacted with CH2O, CH3COCH3, Br2, and ClSi(CH3)3. In addition, the compound was subjected to hydrosilylation, entered into the diene condensation with hexachlorocyclopentadiene, and reacted with NaI, morpholine, and piperidine.

Keywords

Diene CH2O Piperidine Morpholine CH3COCH3 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

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    O. G. Yarosh, N. V. Komarov, and Z. G. Ivanova, Izv. Akad. Nauk SSSR, Ser. Khim., 2122 (1972).Google Scholar
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Copyright information

© Plenum Publishing Corporation 1977

Authors and Affiliations

  • O. G. Yarosh
    • 1
  • T. D. Burnashova
    • 1
  • M. G. Voronkov
    • 1
  1. 1.Irkutsk Institute of Organic ChemistrySiberian Branch of the Academy of Sciences of the USSRUSSR

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