Skip to main content
SpringerLink
Log in

Study of the conformations of certain 1,4-cyclohexenediones and 1, 4-cyclohexanediones

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The 3,6-cyclohexenedione ring, condensed in the 4,5 positions with a three-membered ring or a bicyclic system, exists in the syn-boat conformation.

  2. 2.

    1,4-Dihydronaphthalene oxide exists in the anti-boat conformation in solution.

  3. 3.

    The trans oxides of Δ3-caren-2-one and Δ3-carene-2,5-dione exist in forms showing pseudo-equatorial and pseudo-axial oxide ring orientations.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. A. N. Vereshchagin, S. G. Vul'fson, and B. A. Arbuzov, Izv. Akad. Nauk SSSR, Ser. Khim., 1026 (1974).

  2. A. N. Vereshchagin, A. P. Anastas'eva, and B. A. Arbuzov, Izv. Akad. Nauk SSSR, Ser. Khim., 1420 (1971).

  3. B. A. Arbuzov, A. N. Vereshchagin, S. G. Vul'fson, and A. A. Solov'ev, Izv. Akad. Nauk SSSR, Ser. Khim., 1291 (1972).

  4. A. N. Vereshchagin, S. G. Vul'fson, L. S. Panfilova, A. A. Solov'ev, and B. A. Arbuzov, Izv. Akad. Nauk SSSR, Ser. Khim., 1575 (1972).

  5. B. A. Arbuzov, V. A. Naumov, and L. F. Shatrukov, Dokl. Akad. Nauk SSSR,163, 335 (1965).

    Google Scholar 

  6. B. A. Arbuzov, A. N. Vereshchagin, S. G. Vul'fson, and Z. G. Isaeva, Izv. Akad. Nauk SSSR, Ser. Khim., 1966 (1968).

  7. B. A. Arbuzov, Yu. Yu. Samitov, A. V. Aganov, and Yu. L. Kleiman, Dokl. Akad. Nauk SSSR,184, 341 (1968).

    Google Scholar 

  8. B. A. Arbuzov, A. P. Timosheva, S. G. Vul'fson, and A. N. Vereshchagin, Izv. Akad. Nauk SSSR, Ser. Khim., 1761 (1973).

  9. A. N. Vereshchagin and S. G. Vul'fson, Zh. Strukt. Khim.,9, 1090 (1968).

    Google Scholar 

  10. B. A. Arbuzov, L. A. Grozina, and A. N. Vereshchagin, Izv. Akad. Nauk SSSR, Ser. Khim., 2370, 2377 (1969).

    Google Scholar 

  11. B. A. Arbuzov, A. N. Vereshchagin, S. G. Vul'fson, and E. M. Kharicheva, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk, 2183 (1972).

  12. S. G. Vul'fson, A. N. Vereshchagin, and B. A. Arbuzov, Dokl. Akad. Nauk SSSR,209, 885 (1973).

    Google Scholar 

  13. A. N. Vereshchagin, O. N. Nuretdinova, L. Z. Nikonova, and B. A. Arbuzov, Izv. Akad. Nauk SSSR, Ser. Khim., 758 (1971).

  14. V. A. Naumov and V. M. Bezzubov, Dokl. Akad. Nauk SSSR,171, 634 (1966).

    Google Scholar 

  15. L. P. Acharya, Tetrahedron Lett.,1966, 4117.

  16. A. P. Timosheva, S. G. Vul'fson, L. I. Sorochinskaya, A. N. Vereshchagin, and B. A. Arbuzov, Izv. Akad. Nauk SSSR, Ser. Khim., 865 (1975).

  17. W. K. Grant and J. C. Speakman, J. Chem. Soc., 3753 (1958).

  18. W. D. P. Burns, M. S. Carson, W. Cocker, and P. V. R. Shannon, J. Chem. Soc., C, 3073 (1968).

    Google Scholar 

  19. P. H. Boyle, W. Cocker, D. H. Grayson, and P. V. R. Shannon, J. Chem. Soc., C, 1073 (1971).

    Google Scholar 

  20. L. F. Fieser, W. P. Campbell, E. M. Fry, and M. D. Gates, J. Am. Chem. Soc.,61, 3216 (1939).

    Google Scholar 

  21. O. Diels and K. Aider, Ber.,62, 2337 (1929).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Branch of the Academy of Sciences of the USSR, USSR

    B. A. Arbuzov, S. F. Vul'fson, A. N. Karaseva, G. Sh. Bikbulatova & A. N. Vereshchagin

Authors
  1. B. A. Arbuzov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. F. Vul'fson
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. N. Karaseva
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. G. Sh. Bikbulatova
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. N. Vereshchagin
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp.1780–1784, August, 1976.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Arbuzov, B.A., Vul'fson, S.F., Karaseva, A.N. et al. Study of the conformations of certain 1,4-cyclohexenediones and 1, 4-cyclohexanediones. Russ Chem Bull 25, 1677–1681 (1976). https://doi.org/10.1007/BF00921426

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00921426

Keywords

Search

Navigation