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Studies by the EPR method of radicals formed in the reaction of hydrogen atoms with benzene

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

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Summary

  1. 1.

    We have studied the EPR spectra of the radicals formed in the reaction of hydrogen atoms and benzene in the gas phase at 20 and 200° and frozen with liquid nitrogen.

  2. 2.

    The chief reaction product at 20° is the radical C6H7; at higher temperatures in the reaction zone up to 200° there is also formed in considerable amount radicals apparently of the type C6H5.

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Literature cited

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences, USSR

    L. I. Avramenko, N. Ya. Kuben, R. V. Kolesnikova, V. A. Tolkachev & I. I. Chkheidze

Authors
  1. L. I. Avramenko
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  2. N. Ya. Kuben
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  3. R. V. Kolesnikova
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  4. V. A. Tolkachev
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  5. I. I. Chkheidze
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Additional information

The authors thank Yu. N. Molin for discussing the results.

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Avramenko, L.I., Kuben, N.Y., Kolesnikova, R.V. et al. Studies by the EPR method of radicals formed in the reaction of hydrogen atoms with benzene. Russ Chem Bull 11, 1986–1988 (1962). https://doi.org/10.1007/BF00921364

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  • DOI: https://doi.org/10.1007/BF00921364

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