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Some characteristics of equilibrium transformations of substituted cyclopentadienes

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    We have studied by infrared spectra the successive transformations of 5-deuterocyclopentadiene (VI) into the equilibrium mixture of monodeuterocyclopentadienes.

  2. 2.

    The conversion takes place by the scheme IV⇌1-deuterocyclopentadiene⇌2-deuterocyclopentadiene.

  3. 3.

    In all probability the stepwise character of the reciprocal transformations of cyclopentadiene isomers is a general rule.

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Literature cited

  1. V. A. Mironov, E. V. Sobolev, and A. N. Elizarova, Dokl. AN SSSR143, 1112 (1962).

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  2. V. A. Mironov, T. M. Fadeeva, E. V. Sobolev, and A. N. Elizarova, Zh. Obshch. khimii (1962) (in press).

  3. V. A. Mironov, E. V. Sobolev, and A. N. Elizarova, Dokl. AN SSSR (1962) (in press).

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Communication 9 in the series “Substituted Cyclopentadienes and Related Compounds.”

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Mironov, V.A., Sobolev, E.V. & Elizarova, A.N. Some characteristics of equilibrium transformations of substituted cyclopentadienes. Russ Chem Bull 11, 1983–1984 (1962). https://doi.org/10.1007/BF00921362

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  • DOI: https://doi.org/10.1007/BF00921362

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