Summary
-
1.
Absolute adsorption isotherms have been obtained for n-butylamine and diethylamine vapor along with absorption from solutions in n-heptane on silica gel and aluminum oxide.
-
2.
Either in the vapor form or from solutions in n-heptane, the amines are to a considerable extent irreversibly adsorbed on hydrated silica gel and aluminum oxide surfaces.
-
3.
The amine molecules are more densely adsorbed from liquid solutions than from vapors, the area occupied by a molecule in the dense adsorbed layer being 20–25 A2 for adsorption from solutions, and 35–45 A2 for adsorption from vapors.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Literature cited
O. M. Dzhigit, N. N. Mikos-Avgul', K. D. Shcherbakova, and A. V. Kiselev, Dokl. AN SSSR70, 141 (1950); L. D. Belyakova and A. V. Kiselev, Zh. Fiz. khimii33, 1534 (1959).
C. C. Ballard, E. C. Broge, R. K. Iler, D. S. St. John, and I. R. McWhorter, J. Phys. Chem.65, 20 (1961).
I. V. Drogaleva, A. V. Kiselev, A. Ya. Korolev, and Yu. A. Él'tekov, Kolloid Zh.24 152 (1962).
W. Stöber, Kolloid.-Z.145, 17 (1956).
A. V. Kiselev, N. V. Kovaleva, A. Ya. Korolev, and K. D. Shcherbakova, Dokl. AN SSSR124, 617 (1959); I. Yu. Babkin, V. S. Vasil'eva, I. V. Drogaleva, A. V. Kiselev, A. Ya. Korolev, and K. D. Shcherbakova, Dokl. AN SSSR129, 131 (1959).
A. V. Kiselev and V. V. Kulichenko, Dokl. AN SSSR93, 101 (1953).
R. M. Barrer and D. M. MacLeod, Trans. Faraday Soc.51, 1290 (1955).
G. Bauer and W. Stöber, Kolloid.-Z.167, 27 (1959).
F. E. Bartell and D. G. Dobay, J. Amer. Chem. Soc.72, 4388 (1950).
D. G. Dobay and F. E. Bartell, J. Amer. Chem. Soc.73, 308 (1951).
M. I. Brown and A. G. Foster, J. Chem. Soc. 1952, 1139.
M. I. Brown and A. G. Foster, J. Phys. Chem.56, 733 (1952).
O. Sieskind and R. Wey, Compt. rend.247, 74 (1958).
I. E. Neimark and V. M. Chertov, Dokl. AN SSSR138, 877 (1961).
J. I. Kipling and D. B. Peakall, J. Chem. Soc. 1958, 189, 3899.
L. Dintenfass, Kolloid.-Z.161, 60, 70 (1958).
V. A. Vreving, A. V. Kiselev, and Yu. A. El'tekov, Dokl. AN SSSR86, 349 (1952).
Yu. A. E'l'tekov, Combined adsorption set-up [in Russian] VITÉIN (1961).
A. V. Kiselev and Yu. A. Él'tekov, Dokl. AN SSSR100, 107 (1955).
A. E. Guggenheim and A. K. Adam, Proc. Roy. Soc. A139, 218 (1933).
A. V. Kiselev, Uspekhi khimii25, 705 (1956).
C. G. Shull, P. B. Elin, and L. C. Roess, J. Amer. Chem. Soc.70, 1410 (1948).
A. V. Kiselev, in collection “Methods of investigating the structure of highly disperse and porous bodies” Volume 2 [in Russian], Academy of Sciences Press USSR (1958), p. 47.
S. Brunnauer, P. H. Emmett, and E. Teller, J. Amer. Chem. Soc.60, 309 (1938).
A. V. Kiselev and Yu. A. Él'tekov, Zh. Fiz. khimii31, 250 (1957).
A. A. Isiikyan, A. A. Kiselev, and B. A. Frolov, Zh. Fiz. khimii33, 389 (1959).
O. M. Dzhigit, A. V. Kiselev, and G. G. Muttik, Kolloidn Zh.23, 553 (1961).
N. G. Yaroslavskii and A. N. Terenin, Dokl. AN SSSR66, 885 (1949).
R. P. Eischens, Z. Electrochem.60, 782 (1956).
A. M. Rubinshtein, Yu. A. Él'tekov, and T. R. Brueva, Izv. AN SSSR Old. khim. n. 1960, 2107.
V. K. Semenchenko, Kolloidn Zh.9, 125 (1947).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Aktanova, S., Kiselev, A.V. & Él'tekov, U.A. Adsorption of aliphatic amines on aluminum oxide and silica. Russ Chem Bull 11, 1849–1856 (1962). https://doi.org/10.1007/BF00921337
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00921337