Synthesis of acetic acid N-substituted amides and oligomerization of ethylene during its reaction with mercuric acetate in an amine medium

  • B. K. Nefedov
  • N. S. Sergeeva
  • Ya. T. éidus
Brief Communications


Ethylene oligomerizes to a mixture of hexenes and octenes in the presence of the system: amine-Hg(CH3COO)2, at 200–270‡ and a pressure of 50–70 atm; the corresponding acetic acid N-substituted amide is formed at the same time.


Acetic Ethylene Acetic Acid Hexenes Amide 
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Literature cited

  1. 1.
    B. K. Nefedov, V. A. Petukhov, and Ya. T. éidus, Izv. Akad. Nauk SSSR, Ser. Khim.,1973, 2705.Google Scholar
  2. 2.
    E. J. Mechan, I. M. Kolthoff, C. Auerbach, and H. Minato, J. Am. Chem. Soc.,83, 2232 (1961).Google Scholar
  3. 3.
    W. C. E. Higginson and P. Wright, J. Chem. Soc.,1955, 1551.Google Scholar
  4. 4.
    J. W. Cahn and R. E. Powell, J. Am. Chem. Soc.,76, 2568 (1954).Google Scholar
  5. 5.
    A. A. Slinkin, B. K. Nefedov, A. V. Kucherov, M. I. Loktev, and Ya. T. éidus, Izv. Akad, Nauk SSSR, Ser. Khim.,1973, 2163.Google Scholar
  6. 6.
    B. A. Dolgoplosk and E. I. Tinyakova, Oxidation—Reduction Systems as Sources of Free Radicals [in Russian], Nauka (1972).Google Scholar
  7. 7.
    B. K. Nefedov, N. S. Sergeeva, and Ya. T. éidus, Izv. Akad. Nauk SSSR, Ser. Khim.,1974, 135.Google Scholar
  8. 8.
    R. Mecke and F. Langenbucher, Infrared Spectra of Selected Chemical Compounds, Heyden and Son Ltd., London (1965).Google Scholar

Copyright information

© Plenum Publishing Corporation 1975

Authors and Affiliations

  • B. K. Nefedov
    • 1
  • N. S. Sergeeva
    • 1
  • Ya. T. éidus
    • 1
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of Sciences of the USSRMoscow

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