Dimerization of 2, 3,3-trichloropropene

  • R. G. Gasanov
  • K. A. Kochetkov
Organic and Biological Chemistry


  1. 1.

    Using peroxide initiation and UV irradiation, the dimerization rate of 2,3,3-trichloropropene was studied in the range 50–70‡.

  2. 2.

    The dimerization is stereoselective, with the predominant formation of trans-1,2,4,5-tetrachloro-4-dichloromethylpentene. A reaction scheme was proposed that satisfies the obtained experimental data.



Experimental Data Peroxide Reaction Scheme Predominant Formation Peroxide Initiation 
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Literature cited

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Copyright information

© Plenum Publishing Corporation 1975

Authors and Affiliations

  • R. G. Gasanov
    • 1
  • K. A. Kochetkov
    • 1
  1. 1.Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRMoscow

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