Dimerization of 2, 3,3-trichloropropene
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Using peroxide initiation and UV irradiation, the dimerization rate of 2,3,3-trichloropropene was studied in the range 50–70‡.
The dimerization is stereoselective, with the predominant formation of trans-1,2,4,5-tetrachloro-4-dichloromethylpentene. A reaction scheme was proposed that satisfies the obtained experimental data.
KeywordsExperimental Data Peroxide Reaction Scheme Predominant Formation Peroxide Initiation
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